KINETICS AND MECHANISM OF OXIDATION OF P-ANISIDINE BY FE(III) SOLUTION IN ACIDIC MEDIUM

MANSOUR, MOHAMED A. (2010) KINETICS AND MECHANISM OF OXIDATION OF P-ANISIDINE BY FE(III) SOLUTION IN ACIDIC MEDIUM. Al-Azhar Bulletin of Science, 21 (1). pp. 209-216. ISSN 1110-2535

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Official URL: https://doi.org/10.21608/absb.2010.7349

Abstract

Kinetics of oxidation of p-anisidine by Fe(III) ion was studied spectrophotometry in acidic medium. The rate constant was found to increase with increasing p-anisidine and hydrogen ion concentrations. The order of reaction was found to be first order with respect to both Fe(III) ion and p-anisidine concentration. The suggested mechanism involves the interaction of the reactive species of the reactants to form the activated complex which decompose in a rate determining step to products. The rate law was derived and activation parameters are calculated to be H* = 47 kJ mol-1 and S* = -148.6 JK-1 mol-1

Item Type:	Article
Subjects:	Pacific Library > Medical Science
Depositing User:	Unnamed user with email support@pacificlibrary.org
Date Deposited:	28 Oct 2024 08:11
Last Modified:	28 Oct 2024 08:11
URI:	http://editor.classicopenlibrary.com/id/eprint/1768

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